Preheat your oven to 400°F (200°C).
Season chicken thighs with paprika, garlic powder, onion powder, salt, and black pepper.
Heat 1 tablespoon olive oil in a large oven-safe skillet over medium-high heat.
Sear chicken thighs skin-side down for 3–4 minutes until golden. Flip and cook for another 2 minutes.
Remove chicken temporarily. Add rice to the same pan and stir for 1 minute.
Pour in the chicken broth. Stir and bring to a light simmer.
Place the chicken thighs on top of the rice.
Cover with foil and bake for 25 minutes.
Remove foil. Scatter broccoli florets around the chicken. Drizzle with 1 tablespoon olive oil.
Return to the oven and bake uncovered for another 10–15 minutes, until chicken is cooked through (internal temp 165°F/74°C) and broccoli is tender.
Rest the dish for 5 minutes before serving.
Garnish with lemon juice and parsley if desired.